| Radium | |||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 88Ra | |||||||||||||||||||||
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| Appearance | |||||||||||||||||||||
| General properties | |||||||||||||||||||||
| Name, symbol, number | radium, Ra, 88 | ||||||||||||||||||||
| Element category | alkaline earth metals | ||||||||||||||||||||
| Group, period, block | 2, 7, s | ||||||||||||||||||||
| Standard atomic weight | 226.0273 | ||||||||||||||||||||
| Electron configuration | [Rn] 7s2 [1] 2, 8, 18, 32, 18, 8, 2 [1] File:Electron shell 088 Radium - no label.svg.png | ||||||||||||||||||||
| History | |||||||||||||||||||||
| Discovery | Pierre Curie and Marie Curie (1898) | ||||||||||||||||||||
| First isolation | Marie Curie (1902) | ||||||||||||||||||||
| Physical properties | |||||||||||||||||||||
| Phase | soild | ||||||||||||||||||||
| Density (near r.t. | (0 °C, 101.325 kPa)
5.5 g/cm3 | ||||||||||||||||||||
| Melting point | 973 K | ||||||||||||||||||||
| Boiling point | 2010 K | ||||||||||||||||||||
| Heat of fusion | 8.5 kJ·mol-1 | ||||||||||||||||||||
| Heat of vaporization | 113 kJ·mol-1 | ||||||||||||||||||||
| Vapor pressure | |||||||||||||||||||||
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| Atomic properties | |||||||||||||||||||||
| Oxidation states | 2+ | ||||||||||||||||||||
| Electronegativity | 0.9 (Pauling Scale) | ||||||||||||||||||||
| Ionization energies | 509.3 KJ/mol | ||||||||||||||||||||
| Atomic radius | 215 pm | ||||||||||||||||||||
| Covalent radius | 221±2 pm | ||||||||||||||||||||
| Van der Waals radius | 283 pm | ||||||||||||||||||||
| Crystal structure | Cubic body centered | ||||||||||||||||||||
| Magnetic ordering | Nonmagnetic | ||||||||||||||||||||
| Electrical resistivity | (20 °C) 1 µΩ·m | ||||||||||||||||||||
| Thermal conductivity | (300 K) 18.6 mW/(m/K) | ||||||||||||||||||||
| CAS registry number | 7440-14-4 | ||||||||||||||||||||
| v • t • e • r | |||||||||||||||||||||
The NEW Periodic Table Song (In Order)
Radium is a chemical element with symbol Ra and atomic number 88. Radium is an almost pure-white alkaline earth metal, but turns black on exposure to air. This unusual color occurs because Ra reacts with nitrogen rather than oxygen in the air. All isotopes of radium are highly radioactive, with the most stable isotope being radium-226, which has a half-life of 1600 (+/- 7) years and decays into 222Rn.
Since the only radium isotopes existing in the earth today are within decay chains of the long-lived nuclides 232Th, 235U, and 238U, it is possible to provide a standard atomic weight for radium that will not change in the forseeable future. There are four current radium isotopes: 228Ra, 226Ra, 224Ra, and 223Ra. Two other isotopes are reported to be present, but they are daughters of 237Np. 237Np itself forms via two neutron captures (and substantial loss due to induced fission of 235U. using neutrons provided by the rare spontaneous fission branch of 238U. Production of 225Ra and 221Ra is lost in the noise of things which happen too rarely to care about.
Half-lives and branching ratios are accurately known for all four isotopes. An overall branch ratio from its chain head to each Ra isotope can be computed by multiplying individual branch ratios at each step in a chain of transmutations from head to the target Ra isotope and summing where possible decay paths diverge and recombine. Equilibrium occurs when the target isotope decays at a rate equal to the chain head's decay rate times the overall branch ratio from head to target. Equilibrium (atomic) concentration is overall branch ratio multiplied by half-life of the target divided by half-life of the head. Atomic masses are also known with precision for all four Ra isotopes. Normalizing concentration to 1 and multiplying normalized concentration of each isotope by its atomic mass gives a set of partial masses which can be summed to give the overall atomic weight reported in the infobox.
Radium, in the form of radium chloride, was discovered by Marie Curie and Pierre Curie in 1898. They extracted the radium compound from uraninite and published the discovery at the French Academy of Sciences five days later. Radium was isolated in its metallic state by Marie Curie and André-Louis Debierne through the electrolysis of radium chloride in 1910. Between radium's discovery and acceptance of our current model of the nucleus, people gave names like radium A and radium C2 to several isotopes of other elements that are decay products of radium-226.
In nature, radium is found in uranium ores in trace amounts (up to 1/7 gram per ton of uraninite). Radium is not necessary for living organisms, and adverse health effects are likely when it is incorporated into biochemical processes because of its radioactivity and chemical reactivity. It should be noted that uranium is present in most surface rocks and soils at around the one atom per million level. There are no branches in the decay chain from 238U to 226Ra, so the Ra/U molar concentration ratio equals the ratio of their half-lives, which means 226Ra is present in most surface rocks in soils - at a concentration under a part per trillion.
There are reports of Ra leaching into drilling mud. Even if it is enriched by a factor of 1000, it's present in less than a part per billion - which is on the order of magnitude for limiting concentration in ambient air of agents such as VX or GB (Sarin). While its concentration can rise well above the parts per billion level, that can only happen if a boring passes through a uranium-rich zone, something likely to be of interest to those funding the boring.
Radium has been predicted to form isotopes between the neutron dripline at approximately 295Ra down to 186Ra, of which those isotopes between 234Ra and 202Ra (as well as 12 isomers) have been observed. 227Ra and heavier isotopes decay by beta emission. Except for 228Ra, all half-lives are less than 94 minutes and all but two are less than 5 minutes. 225Ra also beta-decays, with a relatively long half-life of 14.9 days. Between 222Ra and 215Ra all isotopes decay exclusively by alpha emission and have half-lives under 40 sec. (This reflects instability above the neutron shell closure at N = 126.) At 214Ra, positron decay appears as an alternative mode to alpha decay. As A declines, half-lives and positron-emission branch ratios decline until decay is purely alpha emission. The very lightest Ra isotopes decay by proton emission.
| 9-Period Periodic Table of Elements | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 1 | 1 H |
2 He | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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| 2 | 3 Li |
4 Be |
5 B |
6 C |
7 N |
8 O |
9 F |
10 Ne | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 3 | 11 Na |
12 Mg |
13 Al |
14 Si |
15 P |
16 S |
17 Cl |
18 Ar | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 4 | 19 K |
20 Ca |
21 Sc |
22 Ti |
23 V |
24 Cr |
25 Mn |
26 Fe |
27 Co |
28 Ni |
29 Cu |
30 Zn |
31 Ga |
32 Ge |
33 As |
34 Se |
35 Br |
36 Kr | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 5 | 37 Rb |
38 Sr |
39 Y |
40 Zr |
41 Nb |
42 Mo |
43 Tc |
44 Ru |
45 Rh |
46 Pd |
47 Ag |
48 Cd |
49 In |
50 Sn |
51 Sb |
52 Te |
53 I |
54 Xe | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 6 | 55 Cs |
56 Ba |
57 La |
58 Ce |
59 Pr |
60 Nd |
61 Pm |
62 Sm |
63 Eu |
64 Gd |
65 Tb |
66 Dy |
67 Ho |
68 Er |
69 Tm |
70 Yb |
71 Lu |
72 Hf |
73 Ta |
74 W |
75 Re |
76 Os |
77 Ir |
78 Pt |
79 Au |
80 Hg |
81 Tl |
82 Pb |
83 Bi |
84 Po |
85 At |
86 Rn | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 7 | 87 Fr |
88 Ra |
89 Ac |
90 Th |
91 Pa |
92 U |
93 Np |
94 Pu |
95 Am |
96 Cm |
97 Bk |
98 Cf |
99 Es |
100 Fm |
101 Md |
102 No |
103 Lr |
104 Rf |
105 Db |
106 Sg |
107 Bh |
108 Hs |
109 Mt |
110 Ds |
111 Rg |
112 Cn |
113 Nh |
114 Fl |
115 Mc |
116 Lv |
117 Ts |
118 Og | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 8 | 119 Uue |
120 Ubn |
121 Ubu |
122 Ubb |
123 Ubt |
124 Ubq |
125 Ubp |
126 Ubh |
127 Ubs |
128 Ubo |
129 Ube |
130 Utn |
131 Utu |
132 Utb |
133 Utt |
134 Utq |
135 Utp |
136 Uth |
137 Uts |
138 Uto |
139 Ute |
140 Uqn |
141 Uqu |
142 Uqb |
143 Uqt |
144 Uqq |
145 Uqp |
146 Uqh |
147 Uqs |
148 Uqo |
149 Uqe |
150 Upn |
151 Upu |
152 Upb |
153 Upt |
154 Upq |
155 Upp |
156 Uph |
157 Ups |
158 Upo |
159 Upe |
160 Uhn |
161 Uhu |
162 Uhb |
163 Uht |
164 Uhq |
165 Uhp |
166 Uhh |
167 Uhs |
168 Uho |
169 Uhe |
170 Usn |
171 Usu |
172 Usb | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 9 | 173 Ust |
174 Usq | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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